Kythnos and Kea (also known as Tzia) are the first two islands of the western Cyclades, the ones closest to Athens and the port of Lavrio. Both are weekend escapes for Athenians rather than international hotspots, which is exactly their appeal: real villages, uncrowded coves and a pace of life that has little to do with the cruise-ship islands further south.
Heading north from Kythnos to Kea makes sense on a western Cyclades trip that finishes near Athens. Kea is the greener and hillier of the two, with old paths linking its villages and a hilltop capital, Ioulida. From Korissia, its port, frequent boats run to Lavrio, so Kea is a comfortable last stop before the mainland and Athens airport.
The limitation is the timetable. Ferryhopper lists this direct crossing on just two days a week, all year, almost entirely on Blue Star Ferries. That means your dates need to follow the boat. Check which days it sails in the weeks you are travelling before you book rooms on either island, and have a fallback in mind if the day does not suit.
On the plus side, it is cheap and quick. One adult started at €6.50 when we checked, and the crossing takes under an hour and a half. If the direct boat does not fit, you can always go from Kythnos to Lavrio and on to Kea, since both of those routes run far more often.